Harry Moore uses a volunteer recruitment example to demonstrate how ArcGIS for Desktop users can access and use services available in ArcGIS Online for their daily tasks
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The ready to use service folder is populated only after signing into ArcGIS Online. Also, content only appears when an organizational account is used; a Public ArcGIS Online account does not have access to these services. Lastly, this feature is only available with certain releases of desktop. Please see the section titled Legacy in this link for more information: http://resources.arcgis.com/en/help/main/10.2/index.html#/Connecting_ArcMap_to_ArcGIS_Online_network_analysis_services/0047000001v4000000/
In my Catalog Window, I don't have a Ready To Use Services folder so signing in doesn't put anything in the folder. Any suggestions?